Port Vale face a trip to the Hawthorns later this month after being drawn away at West Bromwich Albion in the Capital One Cup second round.
The draw was made LIVE on Sky Sports following the conclusion of the Doncaster Rovers and Leeds United first round tie.
The last time Vale faced the Baggies away from home was in 2000 when they returned from the division one clash with a point after a goalless draw.
The tie will be played week commencing Monday 24th August and ticket details will be announced in due course.